The Crystal and Molecular Structure of Dichloro Monothiodibenzoylmethanato Indium Monothiodibenzoylmethane InCl2L(LH)

نویسندگان

  • Anil K. Mishra
  • Vishnu D. Gupta
  • Heinrich Nöth
چکیده

Indium trichloride reacts with 2 moles of monothiodibenzoylmethane (LH ) in the presence of sodium acetate to yield InC l2L(LH ). According to an X-ray structure analysis the molecule possesses a hexacoordinated indium atom with two chlorine atoms in cis position and two sulfur atoms in trans position. The symmetry of the molecule is C2 imposed by a crystallographic twofold axis. The unique hydrogen atom, assumed to form an intermolecular hydrogen bridge between oxygen atoms could not be detected in the structure analysis.

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تاریخ انتشار 2012